It's Yuri Lowell from Tales of Vesperia as a Shiny Midnight Lycanroc. Pretty much fits him the most out of all the Pokemon, I think.
Experimenting with a new shading style here. I quite prefer this one and will probably continue it into the future.
Other Tales of Vesperia Characters:
Estelle (as Audino): Nightingale
Flynn Scifo (as Midday Lycanroc): Wolf Blade